I just had my first go at etching a circuit board in about 25 years. Last time I did it, I laid the board out on translucent grid paper using sticky pads and tape, and transferred to photosensitive boards.
This time I used Eagle CAD, and blue press-n-peel. I tried using a method that's been documented online, where you print onto cheap magazine paper and then dissolve that away in water. Screwed around for about 3 hours with that. I'm sure someone got it to work, but not me. It turns out I bought some press-n-peel blue transfer material about 12 years ago, and amazingly enough I actually stumbled upon it 2 days ago.
My printer (brother color laser) is really finicky about nonstandard paper, and wound up crunching my sheet of press-n-peel when it finally fed it; it took 5 tries to get it to pick it up. Finally I found a solution online, which is to print on plain paper, then cut out a piece of press-n-peel an inch or so larger than the pattern and tape it over the printed (centered) image on the paper (using the previous print as a location guide) then feed that piece of paper through again so the image is now printed on the press-n-peel. This also allows you to cut out and use only a small amount of press-n-peel. You must use masking tape, others will wreck the printer.
I etched using 1 part hydrochloric acid and 2 parts hydrogen peroxide. This worked great. In contrast to the traditional ferric chloride, this mixture does not stain everything it touches and it's fairly clear so you can watch progress more easily. The fumes are fairly irritating to the mucous membranes from what I've read, though not actually toxic as such. I just cracked a window and had no problems. Another advantage is that apparently this stuff can be refreshed by bubbling air through it; it becomes acid cupric chloride.
The etch isn't perfect, but I learned a lot and hopefully the next time it'll go better. Double sided is a real pain this way. I probably should drill a couple of holes in blank areas of the board in opposite corners and print fiduciaries on the board to line them up properly.
